某会议室夏季工况不同送风方式下的气流组织数值模拟研究

采用数值模拟软件对××大学科技馆某小型会议室进行数值模拟,以实际测量的数据为边界条件,建立合适的数学和物理模型,得到温度场、速度场以及空气品质场等模拟结果,通过对模拟结果的对比分析,得到了最佳的气流组织设计方案,相关结论可以为室内气流组织方案设计与优化提供参考依据。     

Enhanced photocatalytic and antifungal activity of ZnO–Cu2+and Ag@ZnO–Cu2+ materials

Zinc oxide is one of the most versatile nanostructured materials with a broad range of applications. Besides, its physicochemical properties can be tuned easily by synthesis conditions to be optimal for a specific application. In our group, we aim for the production of visible light-active materials with enhanced antimicrobial activity. Thus, we synthesize ZnO–Cu²⁺and Ag@ZnO–Cu²⁺ by using a fast and robust microwave solvothermal reaction. We investigate the limit of solubility of Cu²⁺into ZnO lattice producing Cu doped ZnO materials with different doping levels (1, 2, 3, 4, and 5 at. %, Cu/Zn). We also investigate the role of the copper precursor, using copper(II) acetate or copper(II) sulfate as model precursors. Copper acetate incorporates more efficiently into ZnO lattice by decreasing the Eg value of the doped materials at low doping levels. Furthermore, we study the composites Ag@ZnO–Cu²⁺ aiming to reduce doping levels and to improve antimicrobial activity. Characterization of the materials by different techniques demonstrates their uniform size, purity, crystallinity, and visible light activity. In this study, we evaluate airborne fungal contamination and demonstrate the capacity of ZnO–Cu²⁺ and Ag@ZnO–Cu²⁺ to inhibit fungal growth. We studied the microbiological quality of indoor air (vivarium) by sampling air under different conditions. By sampling air with a photocatalytic prototype, the amount of fungi in the air decreases considerably, particularly fungi that can enter the lung. In addition, ZnO–Cu²⁺ shows excellent antifungal activity against Candida sp at low doses. We use Atomic force microscopy (AFM) and holotomographic microscopy (HTM) to provide further evidence on the capacity of the prepared materials to achieve effective damage to fungal cells and to inhibit biofilm formation.     

极限工况下的管网“互联互通”改进方案

在全国天然气管道“主干互联、区域成网”(以下简称“互联互通”)基础格局逐渐形成的背景下,天然气管网规模日益扩大、管道分支和气源增加,并且分布不集中、输送方向可变,使得输气方案更加灵活,可以更好地解决某些地域的供气紧张问题;但受现有站场和设备的限制,暂不能满足某些多线组合极限工况,使得“互联互通”的初衷难以全部实现。为了使得现有的各输气干线在实现“互联互通”之后可以满足更多的多线组合工况,在分析“互联互通”背景下M管网工况变化的基础上,研发了可以进行水力仿真和压气站方案制订的计算软件,并对3种极限工况下的不同输气量情况进行了可行性试算,进而基于试算结果提出了相应的管网改进建议。研究结果表明:(1)经验证,软件计算误差满足要求;(2)在M管道某处增设压气站或在某些输气站场配置压缩机组;(3) M管网改进调整后,可以完成大部分的多线组合极限工况,真正实现“互联互通”的输气方案。结论认为,该研究成果有助于推进全国天然气管网早日实现“互联互通”。     

基于化学监督的超(超)临界机组关键控制节能指标分析及建议

针对超(超)临界机组参数提高、材质升级,化学技术监督中的监督指标对机组经济性和可靠性影响较大的问题,本文通过机组典型案例分析、技术监督报告、现场实测等,对目前化学监督中影响较大的、关键的技术指标进行了系统性的分析研究。研究结果找出了6项化学监督中超(超)临界机组关键的、影响较大的控制监督指标,且提出了指标控制值和控制方法。这项系统性研究分析方法对指导超(超)临界机组化学监督具有重要的借鉴作用,以控制超(超)临界机组因参数提高和材质升级带来的新问题和新挑战。     

Progress of Air Pollution Control in China and Its Challenges and Opportunities in the Ecological Civilization Era

China’s past economic growth has substantially relied on fossil fuels, causing serious air pollution issues. Decoupling economic growth and pollution has become the focus in developing ecological civilization in China. We have analyzed the three-decade progress of air pollution controls in China, highlighting a strategic transformation from emission control toward air quality management. Emission control of sulfur dioxide (SO₂) resolved the deteriorating acid rain issue in China in 2007. Since 2013, control actions on multiple precursors and sectors have targeted the reduction of the concentration of fine particulate matter (PM_2.5), marking a transition to an air-quality-oriented strategy. Increasing ozone (O₃) pollution further requires O₃ and PM_2.5 integrated control strategies with an emphasis on their complex photochemical interactions. Fundamental improvement of air quality in China, as a key indicator for the success of ecological civilization construction, demands the deep de-carbonization of China’s energy system as well as more synergistic pathways to address air pollution and global climate change simultaneously.     

The reliability of asset management regime of the SROH using air void content of asphalt mixtures

The comparison pairs of cores (each 100 mm apart) from 68 reinstatements sites from various parts of the UK revealed that, the compounding consequences of generic non-homogeneous characteristics of hand laid recipe mixed materials (specified in Specification for the Reinstatement of Openings in Highways (SROH)) and high likeliness of being biased during air void (AV) testing makes the coring method extremely unreliable with very low repeatability and reproducibility. The wide-ranging maximum density reported in every instance in the comparison pair coring experiments meaningfully rationalizes the distorted homogeneity of materials. Although not only maximum density but also bulk density of adjacent cores located only 100 mm apart were found to be varied in the case of every pair in this study. Furthermore, the in situ performance shown by from 50 reinstatements after experiencing 1.5–10 years real-life ageing from various parts of the UK predictably indicates that either the linkage between the reinstatement with non-compliant AV and its impact on footways durability is non-proven or the reported AV content is extremely over estimated. At 95% level of significance, there exists enough evidence to conclude that, due to high uncertainty, very low repeatability and reproducibility and poor reliability with high chances of bias, the assessment of hand laid reinstatement work by AV testing will expose both the contractor and the client to unacceptable risk.     

Impact of air contamination by NOx on the performance of high temperature PEM fuel cells

High temperature PEM fuel cells show enhanced tolerances regarding fuel impurities like CO for use in various applications. However, the impact of air impurities like NO_x on the cell behavior is not completely understood yet. This study provides systematic investigation during 500 h of operation in presence of cathode air containing 10 ppm NO or NO₂. Nitrogen oxides provoke a strongly and linearly decreasing voltage of 245.3 ± 18.5 μV h⁻¹ and highly comparable damage that verifies similar HT-PEMFC degradation via both oxides. Cyclic voltammetry and electron microscopy reveal the loss of electrochemical catalyst surface by selectively poisoned surface and enforced catalyst particle growth. Impedance spectroscopy reveals besides increased electrode charge transfer resistances an affected proton conductivity. In contrast, SO₂/NO₂ impurity mixture in real occurring ratio causes less voltage decay due to a positive SO₂ impact through H₂SO₄ formation causing further shown and discussed effects like nitrate formation and discharge.     

Evaluation of air blast parameters in block cave mining using particle flow code

Air blast, a sudden mass movement of air, can occur in underground mining system where caving develops an extensive mass of unsupported rock spanning a large void. Air blast can result in injury to mine personnel, damage to equipment or disrupts mine operation. Evaluation of air blast parameters is, therefore, an essential part to develop strategies to mitigate the hazard. The properties of a muckpile or a caved zone are significant factors affecting the magnitude of air blast in particular on the undercut and extraction levels. This research investigates the effect of muckpile properties on air flow using the numerical code, PFC2D. The critical parameters such as thickness, block size and porosity (swell factor) of the muckpile have been studied to quantify how much they could change the magnitude of air pressures and velocities while the air flows through the muckpile. It was found that the porosity of the muckpile is the most effective parameter on the magnitude of air blast and by designing a thick layer of blasted rock with low porosity in the caved zone, the intensity of the air blast can be significantly reduced. The findings of this study can be used to design air blast plugs or bulkheads in order to isolate any potential air blast from the active workings, or to quantify the minimum thickness of the muckpile above extraction levels to manage air blast hazards.     

Study of key parameters in modeling liquid hydrogen release and dispersion in open environment

Hydrogen storage in liquid state is considered key feature to its efficient volumetric density for transportation applications. However, there are several hazards associated with handling liquid hydrogen, e.g. fire, explosion, asphyxiation in indoor accidents, and frostbites due to exposure in extremely low temperatures. Predictive capabilities of liquid hydrogen dispersion are essential for developing emergency response plans and facilitate the understanding of the physical problem. In the present study, the Computational Fluid Dynamics (CFD) methodology is employed to simulate the dispersion of liquid hydrogen based on experiment conducted by the Health Safety Laboratory (HSL), in order to investigate several factors that greatly influence dispersion modeling. The flashed vapour fraction at the pipe exit is estimated assuming isenthalpic expansion combined with the NIST equation of state. Modeling the condensation of ambient humidity and air components (nitrogen and oxygen) and imposing transient wind profile are the main issues addressed by the present study. The Homogeneous Equilibrium Model (HEM model) is compared against the Non-Homogeneous Equilibrium Model (NHEM model) to account for slip effects of the non-vapour phase. To estimate the slip velocity in the NHEM model a methodology (momentum slip model) is employed, which solves along with the conservation equations for the mixture the momentum conservation equation of the non-vapour phase. Comparison of the momentum slip model with the algebraic slip model shows that the latter overestimates the slip velocity for large particles and thus its use needs special attention. Overall satisfactory agreement was found with the experimental data when all the above parameters were modelled.     

空调中分布型主动式热回收系统的分析

利用水或乙二醇对空调系统中的余热进行回收,加热空调系统进口新风,使除湿后的新风达到升温的目的。通过余热利用降低加热新风所需要的燃料,减少了二氧化碳的排放。分析讨论了瑞士Konvekta分布型主动式热回收产品的工作原理、使用效果及发展前景。